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|Title:||Spectral studies of new organic conductor (ETOEDT-PDT-TTF)(2)I-3: Normal mode vibrations of the unsymmetrical pi-electron donor|
Keramidas, Anastasios D.
Tasiopoulos, Anastasios J.
Mousdis, George A.
|Type:||Journal Article (Conference paper)|
|Abstract:||New donor-acceptor (ETOEDT-PDT-TTF)(2)I-3 salt showing the layered structure was synthesized and spectrally characterized. It was shown that unsymmetrical (1,4-thioxane-2,3-diyldithio)-propylenedithiotetrathiafulvalene (ETOEDT-PDT-TTF) donor molecule with its extended shape and flexible form is a good system for salts preparation with numerous short contacts and strong intermolecular interactions. Both, Raman and infrared spectra of the donor and its iodine salt were analyzed and discussed. Important role of C=C vibrations was stressed.|
|Journal Title:||Journal of Molecular Structure|
|Conference name:||9th International Conference on Molecular Spectroscopy|
|Conference location:||Wroclaw, POLAND|
|Conference Start date:||2007-09-12|
|Conference End date:||2007-09-16|
|Subject Category:||Science::Physical and theoretical chemistry|
|Keywords:||TTF-derived donor; Ion-radical salt; IR and Raman spectra; Ab initio calculations|
|Other Identifiers:||DOI: http://dx.doi.org/10.1016/j.molstruc.2007.12.046|
|Journal web Location :||http://www.elsevier.com/locate/molstruc|
|Rights holder:||© 2008 Elsevier B.V. All rights reserved.|
|Notes:||Special Issue SI|
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