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|Title:||Bis[1,2-diphenyl-1,2-ethylenedithiolato(2-)-kS(1),kS(2)] gold: Preparation, structure and properties|
|Author/Creator:||Papavassiliou, George C.|
Anyfantis, George C.
Raptopoulou, Catherine P.
|Type:||Journal Article (Scientific Journal article)|
|Abstract:||Starting from 4,5-diphenyl-1,3-dithiol-2-one, the title complex was prepared and studied. Single crystal X-ray structure determination showed that the complex crystallized in the triclinic system, space group P (1) over bar. It is isostructural with the beta-form of the nickel analogue and the molecules have a dissymmetric structure. Structural and EPR data were found to be close to the theoretically calculated ones. Optical and electrochemical data indicate that the complex is stable in air and could be a candidate material for fabrication of electronic devices.|
|Publisher:||Pergamon-elsevier Science Limited|
|Journal Title:||Polyhedron (incorporating Inorganic and Nuclear Chemistry Letters and Journal of Inorganic and Nuclear Chemistry)|
|Subject Category:||Science::Chemistry (General)|
|Keywords:||Metal 1,2-dithiolenes; Crystal structure; Optical properties; EPR spectra; Redox properties; Chemistry, Inorganic & Nuclear|
|Other Identifiers:||DOI: http://dx.doi.org/10.1016/j.poly.2009.05.045|
|Journal web Location :||http://www.sciencedirect.com/science/journal/02775387|
|Rights holder:||© 2009 Elsevier Ltd. All rights reserved.|
|Notes:||Special Issue SI|
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