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|Title:||New type dithiolene complex based on 4,5-(1,4-dioxane-2,3-diyldithio)-1,3-dithiol ligand: Synthesis, experimental and theoretical investigation|
Manos, M. J.
Tasiopoulos, A. J.
Liakos, D. G.
Mousdis, G. A.
|Type:||Journal Article (Scientific Journal article)|
|Abstract:||A new Nickel complex with an extended multisulfur dithiolene ligand Ni(edodddt)(2) (edodddt = 2,3,4 alpha,8 alpha-tetrahydro-dithiine [2,3-b] [1,4] dioxo-6,7-dithiolene) has been synthesized and characterized by electrochemical measurements, IR, UV-Vis and NMR spectroscopy. Its crystal structure was resolved by X-ray diffraction on a single crystal. DFT calculations were made in order to compare the results with the experimental findings and gain an insight of the properties of this new dithiolene complex.|
|Publisher:||Pergamon-elsevier Science Limited|
|Journal Title:||Polyhedron (incorporating Inorganic and Nuclear Chemistry Letters and Journal of Inorganic and Nuclear Chemistry)|
|Subject Category:||Science::Chemistry (General)|
|Keywords:||Dithiolene complexes; IR and Raman spectra; Ab initio calculations; Crystal structure; Cyclic voltammetry; Chemistry, Inorganic & Nuclear|
|Other Identifiers:||DOI: http://dx.doi.org/10.1016/j.poly.2009.05.031|
|Journal web Location :||http://www.sciencedirect.com/science/journal/02775387|
|Rights holder:||© 2009 Elsevier Ltd. All rights reserved.|
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