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|Title:||Molecular conductors with differently oriented conducting layers, (EDT-TTF)(3)Hg2Br6 and (TMBEDT-TTF)(5)Hg(SCN)(4)-I-x(x)|
|Author/Creator:||Zhilyaeva, E. I.|
Semkin, V. N.
Yudanova, E. I.
Vlasova, R. M.
Torunova, S. A.
Flakina, A. M.
Mousdis, G. A.
Van, K. V.
Lyubovskii, R. B.
Lyubovskaya, R. N.
|Type:||Journal Article (Scientific Journal article)|
|Abstract:||New conducting radical cation salts (EDT-TTF)(3)Hg2Br6, (TMET)(5)Hg(SCN)(4-x)I-x (x approximate to 0.35), and (EDT-TTF)(3)Hg(SCN)(3)I-0.5(PhCl)(0.5) were synthesized. Their conductivities, ESR and polarized reflectance spectra were studied. It was shown that the organic conductors with differently oriented conducting layers (EDT-TTF)(3)Hg2Br6 and (TMET)(5)Hg(SCN)(4-x)I-x (x approximate to 0.35) are characterized by the quasi-one-dimensional character of electron motion. The conductivity along and across conducting layers has a semiconductive character. It was established by ESR and polarized reflectance spectroscopy that the properties of such conductors are a superposition of the properties of individual conducting layers.|
|Publication Place:||NEW YORK|
|Publisher:||Springer New York LLC|
|Journal Title:||Russian Chemical Bulletin|
|Subject Category:||Science::Chemistry (General)|
|Keywords:||molecular conductors based on radical cation salts; electrical conductivity; polarized reflectance spectra; ESR spectra|
|Other Identifiers:||DOI: http://dx.doi.org/10.1007/s11172-010-0247-4|
|Journal web Location :||http://www.springerlink.com/openurl.asp?genre=journal&issn=1066-5285|
|Rights holder:||© SPRINGER|
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