TY - JOUR ID - 10442/17572 A1 - Kostas I.D. A1 - A1 - Tenchiu A.-C. A1 - A1 - Arbez-Gindre C. A1 - A1 - Psycharis V. A1 - A1 - Raptopoulou C.P. Y1 - 2014/// T1 - Room-temperature Suzuki-Miyaura coupling of aryl bromides with phenylboronic acid catalyzed by a palladium complex with an inexpensive nitrogen-containing bis(phosphinite) ligand JF - Catalysis Communications VL - 51 SN - 1566-7367 U3 - 10.1016/j.catcom.2014.03.014 PB - Elsevier SP - 15–18EP - UR - https://hdl.handle.net/10442/17572 N2 - A palladium(II) complex with a known inexpensive and very easily synthesized nitrogen-containing bis(phosphinite) ligand has been prepared and characterized by spectroscopic and crystallographic studies. The ligand is bound to the metal in a P,P-bidentate coordination mode with a bite angle of 98.90°. This complex was found to be an efficient catalyst for room-temperature Suzuki-Miyaura coupling of a variety of aryl bromides with phenylboronic acid. At 0.1 mol% of palladium in DMF/K3PO4 for 24 h, the corresponding biaryls were obtained with 75-92% yields. Activated substrates displayed high yields even within minutes. ER -