Εξειδίκευση τύπου :	Άρθρο σε επιστημονικό περιοδικό
Τίτλος:	Synthesis of (AB)n-, AnBn-, and AxBy-type amphiphilic and double-hydrophilic star copolymers by RAFT polymerization
Δημιουργός/Συγγραφέας:	Skandalis A. [EL] Πίσπας, Στέργιος[EN] Pispas, Stergios
Εκδότης:	John Wiley and Sons Inc
Ημερομηνία:	2019
Γλώσσα:	Αγγλικά
ISSN:	0887-624X
DOI:	10.1002/pola.29447
Περίληψη:	The synthesis, characterization, and postpolymerization functionalization of star copolymers by RAFT polymerization, using ethylene glycol dimethacrylate as the difunctional monomer for core formation via crosslinking, is presented in this work. The “arm first” approach was used for the synthesis of PDMAEMAnPOEGMAn double-hydrophilic mikto-arm stars and PDMAEMAxPLMAy amphiphilic miktoarm stars, while the “core first” approach was used for the synthesis of (PDMAEMA-b-POEGMA)n double-hydrophilic star block copolymers. Methyl iodide was used as the quaternizing agent for the transformation of the star copolymers into strong cationic star polyelectrolytes, through reaction on the dimethylamino groups of PDMAEMA blocks. The stars were characterized at the molecular level by SEC and proton nuclear magnetic resonance. Preliminary light scattering experiments, using THF and H2O as the solvents, were performed in order to get information regarding the solution behavior of the novel star copolymers synthesized.
Τίτλος πηγής δημοσίευσης:	Journal of Polymer Science, Part A: Polymer Chemistry
Τόμος/Κεφάλαιο:	57
Τεύχος:	16
Σελίδες:	1771-1783
Θεματική Κατηγορία:	[EL] Φυσική και θεωρητική χημεία[EN] Physical and theoretical chemistry
Λέξεις-Κλειδιά:	arm first core first light scattering RAFT star copolymers
Αξιολόγηση από ομότιμους (peer reviewed):	Ναι
Κάτοχος πνευματικών δικαιωμάτων:	© 2019 Wiley Periodicals, Inc.
Σημειώσεις:	European Commission, EC; European Social Fund, ESF: MIS-5000432 This research is co-financed by Greece and the European Union (European Social Fund - ESF) through the Operational Program ?Human Resources Development, Education and Lifelong Learning? in the context of the project ?Strengthening Human Resources Research Potential via Doctorate Research? (MIS-5000432), implemented by the State Scholarships Foundation (IKY).
Εμφανίζεται στις συλλογές:	Ινστιτούτο Θεωρητικής και Φυσικής Χημείας (ΙΘΦΧ) - Επιστημονικό έργο