Εξειδίκευση τύπου :	Άρθρο σε επιστημονικό περιοδικό
Τίτλος:	One-Dimensional Organic–Inorganic Hybrid Materials Based on Antimony
Δημιουργός/Συγγραφέας:	[EL] Μούσδης, Γεώργιος Α.[EN] Mousdis, George A. Ganotopoulos N.-M. Barkaoui H. Abid Y. Psycharis V. Savvidou A. Raptopoulou C.P.
Εκδότης:	Wiley-VCH Verlag
Ημερομηνία:	2017
Γλώσσα:	Αγγλικά
ISSN:	1434-1948
DOI:	10.1002/ejic.201700277
Περίληψη:	The rise of lead halide perovskites as light harvesters has stunned the photovoltaic community because of the high efficiencies achieved. Owing to their unique optical and electronic properties, hybrid metal halide perovskites and their application in optoelectronic devices are a hot topic of academic research. Although Pb and Sn hybrids are used in most cases, they present stability and toxicity problems. Therefore, similar compounds with other metals have been investigated. Antimony-based hybrid perovskites are good alternatives to their Pb-based analogues for photovoltaic and other applications. In this paper, we report the synthesis of four organic–inorganic hybrid compounds of the general formula [CH3SC(NH2)2]2SbA5, (A = I, Br, Cl, and Cl/Br). They contain corner-sharing SbX6 octahedra, which form zigzag chains, and the amine groups are located in the free cavities between the chains. Their structural, optical, and vibronic properties were studied, and the results of DFT calculations were compared with the experimental findings to provide insights into the properties of these new compounds.
Τίτλος πηγής δημοσίευσης:	European Journal of Inorganic Chemistry
Τόμος/Κεφάλαιο:	2017
Τεύχος:	28
Σελίδες:	3401-3408
Θεματική Κατηγορία:	[EL] Φυσική και θεωρητική χημεία[EN] Physical and theoretical chemistry
Λέξεις-Κλειδιά:	Antimony Density functional calculations Organic–inorganic hybrid composites Perovskite phases Structure elucidation
Αξιολόγηση από ομότιμους (peer reviewed):	Ναι
Κάτοχος πνευματικών δικαιωμάτων:	© 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Εμφανίζεται στις συλλογές:	Ινστιτούτο Θεωρητικής και Φυσικής Χημείας (ΙΘΦΧ) - Επιστημονικό έργο