Εξειδίκευση τύπου :	Άρθρο σε επιστημονικό περιοδικό
Τίτλος:	One-Pot synthesis of functional poly(methacrylate) by ATRP and 1,8-Diazacyclo-[5,4,0]undec-7-ene catalyzed transesterification
Δημιουργός/Συγγραφέας:	Xu J. Lian W. [EL] Πίσπας, Στέργιος[EN] Pispas, Stergios Zhang G.
Εκδότης:	John Wiley and Sons Inc.
Ημερομηνία:	2014
Γλώσσα:	Αγγλικά
ISSN:	0887-624X
DOI:	10.1002/pola.27346
Περίληψη:	A facile one-pot 1,8-diazacyclo-[5,4,0]undec-7-ene (DBU) catalyzed transesterification/atom transfer radical polymerization (ATRP) strategy has been successfully developed through the combination of copper/DBU-catalyzed ATRP and DBU-catalyzed transesterification reactions. Well-defined poly(methacrylate)s with various side ester groups have been synthesized by ATRP and transesterification of acyl donor 2,2,2-trifluoethyl methacrylate with various alcohols, such as benzyl alcohol, n-butanol, iso-propyl alcohol, methanol, triethylene glycol monomethyl ether, propargyl alcohol, and 6-azido-1-hexanol by the one-pot process. Kinetic studies indicate that the ATRP process proceeded in a controllable manner without the interference of the transesterification reactions. Expansion of the binary system to a higher level ternary system has been successfully achieved by the combination of copper(I)-catalyzed azide-alkyne cycloaddition, transesterification, and ATRP reactions.
Τίτλος πηγής δημοσίευσης:	Journal of Polymer Science, Part A: Polymer Chemistry
Τόμος/Κεφάλαιο:	52
Τεύχος:	20
Σελίδες:	2998-3003
Θεματική Κατηγορία:	[EL] Φυσική και θεωρητική χημεία[EN] Physical and theoretical chemistry
Λέξεις-Κλειδιά:	1,8-diazacyclo-[5,4,0]undec-7-ene ATRP click reaction one-pot poly(methacrylate) transesterification
Αξιολόγηση από ομότιμους (peer reviewed):	Ναι
Κάτοχος πνευματικών δικαιωμάτων:	© 2014 Wiley Periodicals, Inc.
Εμφανίζεται στις συλλογές:	Ινστιτούτο Θεωρητικής και Φυσικής Χημείας (ΙΘΦΧ) - Επιστημονικό έργο