Εξειδίκευση τύπου :	Άρθρο σε επιστημονικό περιοδικό
Τίτλος:	Asymmetric phthalocyanines (A3B type) containing aminophenoxy and hydroxyphenyl-diazenyl-phenoxy substituents
Δημιουργός/Συγγραφέας:	Thimiopoulos A. [EL] Σημαντήρας, Eμμανουήλ[EN] Simandiras, Emmanuel D. Psaroudakis N.
Εκδότης:	Elsevier S.A.
Ημερομηνία:	2019
Γλώσσα:	Αγγλικά
ISSN:	0020-1693
DOI:	10.1016/j.ica.2019.119105
Περίληψη:	In this research new asymmetric metal-phthalocyanine complexes (A3B-type), with Zn2+, Co2+ and Ru2+, bearing aminophenoxy and hydroxyphenyl-diazenyl-phenoxy substituents, were synthetized. The synthetic route to asymmetric Pcs (A3B-type), based on ring expansion method is refined. The photophysical and electrochemical properties of the new phthalocyanines were investigated. In addition to this investigation, a comparative study took place on the effect of the expansion of conjunction on properties of the MPc compound. Moreover, the effect of pH to the ground state electronic absorption spectra of compounds bearing hydroxyphenyl-diazenyl-phenoxy substituents was also studied. Theoretical studies (DFT) were also carried out in order to support the corresponding experimental results.
Τίτλος πηγής δημοσίευσης:	Inorganica Chimica Acta
Τόμος/Κεφάλαιο:	498
Θεματική Κατηγορία:	[EL] Φυσική και θεωρητική χημεία[EN] Physical and theoretical chemistry
Λέξεις-Κλειδιά:	A3B type Cobalt DFT Phthalocyanines Ruthenium Zinc
Αξιολόγηση από ομότιμους (peer reviewed):	Ναι
Κάτοχος πνευματικών δικαιωμάτων:	© 2019 Elsevier B.V.
Εμφανίζεται στις συλλογές:	Ινστιτούτο Θεωρητικής και Φυσικής Χημείας (ΙΘΦΧ) - Επιστημονικό έργο