Εξειδίκευση τύπου :	Άρθρο σε επιστημονικό περιοδικό
Τίτλος:	Halogen–NH2+ interaction, temperature-induced phase transition, and ordering in (NH2CHNH2)PbX3 (X = Cl, Br, I) hybrid perovskites
Δημιουργός/Συγγραφέας:	Kontos, Athanassios G. Manolis, Georgios K. Kaltzoglou, Andreas [EL] Παλλές, Δημήτρης[EN] Palles, Dimitris [EL] Καμίτσος, Ευστράτιος Ι.[EN] Kamitsos, Efstratios I. Kanatzidis, Mercouri G. Falaras, Polycarpos
Εκδότης:	American Chemical Society
Ημερομηνία:	2020
Γλώσσα:	Αγγλικά
ISSN:	1932-7447 1932-7455
DOI:	10.1021/acs.jpcc.9b11334
Περίληψη:	Hybrid organic–inorganic FAPbX3 perovskites (FA = NH2CHNH2+, X = Cl–, Br–, I–) are currently intensively investigated in solar cells. In this study, off-resonance Raman and far-IR absorption spectra of all single-halogen FAPbX3, as well as of mixed-halogen FAPbBr2X derivatives, are reported and analyzed. Vibrations of the PbX6 octahedra and librations of the FA cation lay at frequencies below 250 cm–1, while external and internal FA bands are identified above 200 cm–1. An increase in the frequencies of most vibrational bands is observed upon substituting lighter and more electronegative halides for heavier ones due to strengthening of the electrostatic interaction between X– and the FA NH2+ groups. Variable-temperature Raman measurements are also carried out for FAPbBr3 and FAPbCl3 in the 77–400 K range. Upon cooling, the three Pb–X Raman vibrations of the cubic structure, split into eight separate bands, signaling the transformation to the tetragonal phase at ∼240 K and ∼200 K for FAPbBr3 and FAPbCl3, respectively. At even lower temperatures, a successive phase transformation to low symmetry orthorhombic phases is evidenced. These temperature-induced effects are accompanied by intense narrowing, soft-mode behavior, and/or sudden frequency shift of specific Raman bands, attributed to ordering of the FA cation.
Τίτλος πηγής δημοσίευσης:	The Journal of Physical Chemistry C
Τόμος/Κεφάλαιο:	124
Τεύχος:	16
Σελίδες:	8479–8487
Θεματική Κατηγορία:	[EL] Φυσική και θεωρητική χημεία[EN] Physical and theoretical chemistry [EL] Φασματοσκοπία[EN] Spectroscopy [EL] Χημεία (Γενικά)[EN] Chemistry (General)
Λέξεις-Κλειδιά:	Cations Oscillation perovskites Phase transitions Raman spectroscopy
Κάτοχος πνευματικών δικαιωμάτων:	Copyright © 2020 American Chemical Society
Ηλεκτρονική διεύθυνση στον εκδότη (link):	https://pubs.acs.org/doi/10.1021/acs.jpcc.9b11334
Ηλεκτρονική διεύθυνση περιοδικού (link) :	https://pubs.acs.org/journal/jpccck
Εμφανίζεται στις συλλογές:	Ινστιτούτο Θεωρητικής και Φυσικής Χημείας (ΙΘΦΧ) - Επιστημονικό έργο