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https://hdl.handle.net/10442/19121
Εξειδίκευση τύπου : | Άρθρο σε επιστημονικό περιοδικό |
Τίτλος: | Association of Thermoresponsive Diblock Copolymer PDEGMA-b-PDIPAEMA in Aqueous Solutions: The Influence of Terminal Groups |
Δημιουργός/Συγγραφέας: | Škorňa, Adam Selianitis, Dimitrios [EL] Πίσπας, Στέργιος[EN] Pispas, Stergios![semantics logo](/EIE/image/semantics.png) Štěpánek, Miroslav |
Ημερομηνία: | 2024-07-24 |
Γλώσσα: | Αγγλικά |
ISSN: | 2073-4360 |
DOI: | 10.3390/polym16152102 |
Άλλο: | 39125129 |
Περίληψη: | Aqueous solutions of a thermoresponsive diblock copolymer poly(di-[ethylene glycol] methyl ether methacrylate)-b-poly(2-[diisopropylamino] ethyl methacrylate) (PDEGMA-b-PDIPAEMA) were studied by static, dynamic and electrophoretic light scattering, small-angle X-ray scattering and differential scanning calorimetry. Thermoresponsive behavior of PDEGMA-b-PDIPAEMA was investigated at two pH values, pH = 2, at which the terminal carboxylic group of the PDEGMA chain and the PDIPAEMA block are protonated, and pH = 7, where the carboxyl terminal group is ionized while the PDIPAEMA block is partially deprotonated and more hydrophobic. Both at pH = 2 and 7, PDEGMA-b-PDIPAEMA copolymer underwent extensive association (the size of the aggregates was between 100 and 300 nm), indicating strong interchain interactions. While the measurements confirmed thermoresponsive behavior of PDEGMA-b-PDIPAEMA at pH = 7, no changes in the association with temperature were observed at pH 2 as the thermoresponsivity of PDEGMA was suppressed by hydrogen bonding between carboxylic groups and PDEGMA segments, as well as due to the increased hydrophilicity of the PDIPAEMA block. Fluorescence measurements with pyrene as a fluorescent probe showed that both at pH = 2 and pH = 7 the associates were able to solubilize hydrophobic substances. |
Τίτλος πηγής δημοσίευσης: | Polymers |
Τόμος/Κεφάλαιο: | 16 |
Τεύχος: | 15 |
Θεματική Κατηγορία: | [EL] Φυσική και θεωρητική χημεία[EN] Physical and theoretical chemistry![semantics logo](/EIE/image/semantics.png) [EL] Νανοτεχνολογία[EN] Nanotechnology![semantics logo](/EIE/image/semantics.png) |
Λέξεις-Κλειδιά: | association block copolymers pH-responsive polymers thermoresponsive polymers |
EU Grant: | Excellent Research Teams |
EU Grant identifier: | CZ.02.1.01/0.0/0.0/15_003/0000417-CUCAM |
Κάτοχος πνευματικών δικαιωμάτων: | © 2024 by the authors. Licensee MDPI, Basel, Switzerland. |
Όροι και προϋποθέσεις δικαιωμάτων: | This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https:// creativecommons.org/licenses/by/ 4.0/). |
Ηλεκτρονική διεύθυνση στον εκδότη (link): | https://doi.org/10.3390/polym16152102 |
Εμφανίζεται στις συλλογές: | Ινστιτούτο Θεωρητικής και Φυσικής Χημείας (ΙΘΦΧ) - Επιστημονικό έργο
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